A composite of an adhesive film contains a thermoplastic elastomer selected from rubber-based thermoplastic elastomer or rubber series material, polyethylene-based coupling agent or ethylene vinyl acetate (EVA)-based coupling agent, montan wax, and fatty acid esters with pentaerythritol having five to nine carbons. The adhesive film is typically useful to produce footwear by molding a shoe sole in a mold, and thus, not requiring the conventional labor-consuming and hazardous processes, such as cleaning, primer coating, and bonding processes, to separately produce an outsole, a midsole, and an upper, and then binding together to manufacture a shoe.