A back sheet of solar module with high adhesivity comprises a substrate (3), a layer of fluorine-based film (2), and a layer of fluoro-silicone film (1) or titanium-silicon film (4) formed between the layer of fluorine-based film (2) and the substrate (3), as well as on outer surface of the layer of fluorine-based film (2). A method for manufacturing the back sheet of solar module comprises the treatment on the layer of fluorine-based film (2) and/or substrate (3) with compound of fluoro-silicone or titanium-silicon, so as to coat a layer of fluoro-silicone film (1) or titanium-silicon film (4).