A call switching method and a mobile device are provided that rapidly and conveniently switch calls. The method includes establishing, by the mobile device, a first call with a first device; receiving, by the mobile device, a request for a second call from a second device, during the first call; informing a user of the mobile device of the call request; determining, by the mobile device, whether the user moves the mobile device from a first ear to a second ear; and accepting, by the mobile device, the second call with the second device, when the mobile device is moved from the first ear to the second ear.