An article comprising a plurality of intersecting walls having outer surfaces that define a plurality of cells extending from one end to a second end, wherein the walls forming each cell in a first subset of cells are covered by a barrier layer to form a plurality of heat exchange flow channels, and wherein the walls forming each cell in a second subset of cells different from the first subset of cells, comprise a CO2 sorbent and form reaction flow channels. Heat exchange flow channels allow quick and uniform heating and cooling of the sorbent body. The article may be useful, for example, for removing CO2 from a gas stream.