Invention Grant
US09011592B2 Transparent inorganic-organic hybrid materials via aqueous sol-gel processing
有权
透明无机 - 有机杂化材料通过水溶胶 - 凝胶加工
- Patent Title: Transparent inorganic-organic hybrid materials via aqueous sol-gel processing
- Patent Title (中): 透明无机 - 有机杂化材料通过水溶胶 - 凝胶加工
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Application No.: US14243390Application Date: 2014-04-02
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Publication No.: US09011592B2Publication Date: 2015-04-21
- Inventor: Masahiro Asuka , Wolfgang M. Sigmund
- Applicant: University of Florida Research Foundation, Inc.
- Applicant Address: US FL Gainesville
- Assignee: University of Florida Research Foundation, Inc.
- Current Assignee: University of Florida Research Foundation, Inc.
- Current Assignee Address: US FL Gainesville
- Agency: Saliwanchik, Lloyd & Eisenschenk
- Main IPC: C09D183/02
- IPC: C09D183/02 ; C08L83/00 ; B82Y20/00 ; B82Y30/00 ; C08G77/14 ; C08G77/58 ; C09D183/04 ; C09D183/06 ; C09D183/14 ; G02B1/10 ; C08K3/32 ; C08K3/36

Abstract:
A sol to form an inorganic-organic hybrid coating having a thick highly transparent hard coating is described. The hybrid coating is formed from a combined aqueous sol with least one hydrolyzable silane and at least one hydrolyzable metal oxide precursor where the only organic solvents present are those liberated upon hydrolysis of the silanes and metal oxide precursors. In one embodiment an inorganic-organic hybrid coating is formed by combination of a sol, prepared by the hydrolysis of tetraethoxysilane and γ-glycidoxypropyltrimethoxysilane with an excess of water, and a sol, prepared by the hydrolysis of titanium tetrabutoxide and γ-glycidoxypropyltrimethoxysilane with a deficiency of water. A plastic substrate can be coated with the combined sol and the combined sol gelled to a thickness of at least 5 μm with heating to less than 150° C.
Public/Granted literature
- US20140208982A1 TRANSPARENT INORGANIC-ORGANIC HYBRID MATERIALS VIA AQUEOUS SOL-GEL PROCESSING Public/Granted day:2014-07-31
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