Invention Grant
- Patent Title: Method for producing polyacrylic acid (salt)-based water absorbent resin
- Patent Title (中): 制备聚丙烯酸(盐)基吸水树脂的方法
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Application No.: US14358638Application Date: 2012-11-16
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Publication No.: US09012356B2Publication Date: 2015-04-21
- Inventor: Koji Tachi , Hironori Sato , Kazushi Torii , Hiroyuki Ikeuchi
- Applicant: Nippon Shokubai Co., Ltd.
- Applicant Address: JP Osaka
- Assignee: Nippon Shokubai Co., Ltd.
- Current Assignee: Nippon Shokubai Co., Ltd.
- Current Assignee Address: JP Osaka
- Agency: Roylance, Abrams, Berdo & Goodman, L.L.P.
- Priority: JP2011-251103 20111116
- International Application: PCT/JP2012/079836 WO 20121116
- International Announcement: WO2013/073682 WO 20130523
- Main IPC: C08L33/02
- IPC: C08L33/02 ; C08J3/24 ; C08F20/06 ; A61L15/24 ; A61L15/60 ; C08F220/06 ; C08F120/06

Abstract:
The purpose of the present invention is to provide a method for producing a water absorbent resin having improved physical properties, particularly, improved saline flow conductivity (SFC) and less amount of fine powder. The present invention provides a method for producing a polyacrylic acid (salt)-based water absorbent resin, the method comprising: a polymerization step of supplying as a base material an aqueous solution containing an acrylic acid and/or an acrylic acid salt as a monomer component and polymerizing the monomer in the presence of a polymerization initiator, wherein in the polymerization step, there is used a polymerization apparatus which comprises a polymerization part covered with a case, said polymerization part comprising at least a supply line for supplying the aqueous solution, an external gas supply port, and a gas discharge port, and has a structure that a liquid contact part in contact with the aqueous solution and a gas supplied from the outside of the polymerization apparatus are brought into contact with the aqueous solution during a polymerization, and assuming that a controlled temperature of the liquid contact part is set as TS, a temperature of the gas part is set as TG, and TT is (TS+TG)/2, the polymerization is carried out under temperature conditions satisfying the following Equations 1 to 3: 35° C.≦TS≦85° C., Equation 1: 40° C.≦TG≦90° C., Equation 2: 47° C.≦TT≦73° C. Equation 3:
Public/Granted literature
- US20140371400A1 METHOD FOR PRODUCING POLYACRYLIC ACID (SALT)-BASED WATER ABSORBENT RESIN Public/Granted day:2014-12-18
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