Invention Grant
- Patent Title: Copper (I) complexes for optoelectronic devices
- Patent Title (中): 铜(I)配合物用于光电器件
-
Application No.: US13810848Application Date: 2011-07-20
-
Publication No.: US09024026B2Publication Date: 2015-05-05
- Inventor: Hartmut Yersin , Rafal Czerwieniec , Uwe Monkowius
- Applicant: Hartmut Yersin , Rafal Czerwieniec , Uwe Monkowius
- Applicant Address: DE Bruchsal
- Assignee: Cynora GmbH
- Current Assignee: Cynora GmbH
- Current Assignee Address: DE Bruchsal
- Agency: Harris Beach PLLC
- Priority: DE102010031831 20100720
- International Application: PCT/EP2011/062491 WO 20110720
- International Announcement: WO2012/010650 WO 20120126
- Main IPC: C09K11/06
- IPC: C09K11/06 ; C07D471/04 ; C07F5/02 ; C07F9/50 ; C07F9/6561 ; H01L51/00 ; H01L51/50

Abstract:
The invention relates to neutral mononuclear copper (I) complexes for emitting light and with a structure according to formula (A) in which: M represents: Cu(I); L∩L represents: a single, negatively charged, bidentate ligand; N∩N represents: a diimine ligand (substituted with R and FG), in particular a substituted 2,2′-bipyridine derivative (bpy) or a substituted 1,10-phenanthroline derivative (phen); R represents: at least one sterically demanding substituent for preventing the planarization of the complex in the excited state; FG=functional group, and represents: at least one second substituent for increasing solubility in organic solvents. The substituent can also be used for electron transport or alternatively for hole transport, said functional group being bound to the diimine ligands either directly or by means of suitable bridges; and the copper (I) complex: having a ΔE(S1−T1) value of less than 2500 cm−1 between the lowest excited singlet state (S1) and the triplet state (T1) which lies below; having an emission lifespan of at most 20 μs; having an emission quantum yield of greater than 40%, and a solubility of at least 1 g/L in organic solvents, in particular polar organic hydrocarbons such as acetone, methyl ethyl ketone, benzene, toluene, chlorobenzene, dichlorobenzene, dichloromethane, chloroform, dichloroethane, tetrachloroethylene, alcohols, acetonitrile or water.
Public/Granted literature
- US20130150581A1 COPPER (I) COMPLEXES FOR OPTOELECTRONIC DEVICES Public/Granted day:2013-06-13
Information query