The present invention provides an organic thin film solar cell having a novel photoelectric conversion layer with superior conversion efficiency from light to electricity and superior carrier transportability to an electrode. The photoelectric conversion layer is arranged between a pair of electrodes at least one of which has optical transparency, and comprises a multilayer film formed by alternately laminating an electron-donating organic semiconductor thin film and an electron-accepting thin film. The electron-donating organic semiconductor thin film is formed by organic semiconductor molecules in which cyclic compounds are bound in a linear fashion.