A water analysis measurement arrangement for determining a concentration of ions and/or ionic compounds in an aqueous medium includes a closed buffer solution housing comprising a pH buffer solution. The closed buffer solution housing is configured to communicate with the aqueous medium via an electrolyte bridge. A reference electrode is arranged in the closed buffer solution housing. An amplifier ground is disposed on a ground electrode and is configured to directly contact the aqueous medium. A high-impedance amplifier comprises a first capacitive element arranged between the reference electrode and the amplifier ground. An AC voltage generator is arranged between the amplifier ground and the ground electrode. A measurement electrode is configured to directly contact the aqueous medium. A redundant unit comprises a separate low-impedance redundant electrode arranged in the closed buffer solution housing and a high-impedance redundant electrode amplifier comprising a second capacitive element to the amplifier ground.