Invention Grant
- Patent Title: Negative electrode material for lithium secondary battery and its manufacturing method, and negative electrode for lithium secondary battery, and lithium secondary battery
- Patent Title (中): 锂二次电池用负极材料及其制造方法,锂二次电池用负极和锂二次电池
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Application No.: US13391811Application Date: 2011-12-09
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Publication No.: US09070941B2Publication Date: 2015-06-30
- Inventor: Takashi Mukai , Taichi Sakamoto , Tetsuo Sakai , Kunihiko Tani , Naoto Yamashita , Koichiro Ikeda
- Applicant: Takashi Mukai , Taichi Sakamoto , Tetsuo Sakai , Kunihiko Tani , Naoto Yamashita , Koichiro Ikeda
- Applicant Address: JP Tokyo JP Osaka
- Assignee: National Institute of Advanced Industrial Science and Technology,Isuzu Glass Company, Ltd.
- Current Assignee: National Institute of Advanced Industrial Science and Technology,Isuzu Glass Company, Ltd.
- Current Assignee Address: JP Tokyo JP Osaka
- Agent Dennis A. Bennett
- Priority: JP2011-045698 20110302; JP2011-100039 20110427
- International Application: PCT/JP2011/078622 WO 20111209
- International Announcement: WO2012/117638 WO 20120907
- Main IPC: H01M6/18
- IPC: H01M6/18 ; H01M4/36 ; H01M4/136 ; H01M4/1397 ; H01M4/58 ; H01M4/62 ; H01M10/0525 ; H01M4/66

Abstract:
[Object] The object is to provide a negative electrode material for a lithium secondary battery, wherein a sulfide-based negative electrode with water-resistant properties can exert excellent cycle characteristics and high output performance while maintaining a high discharge capacity and there is no precipitation of lithium dendrites during charge at low temperature.[Means for Solving Problems] A negative electrode material for a lithium secondary battery comprising sulfur and sulfide glass including the following components (i) and (ii):(i) at least one or more elements selected from a group consisting of Sb, As, Bi, Ge, Si, Cu, Zn, Pd, In and Zr; and(ii) at least one or more elements selected from a group consisting of Se, Te, Ga, Sn, Pb, Cd, Al, Fe, Mg, Ca, Co, Ag, Sr, P and Ba, wherein the ratio of the above components is sulfur: 40-80 mol %, (i): 1-50 mol % and (ii): 1-50 mol %, respectively.
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