Invention Grant
- Patent Title: Polyacrylic acid-type water absorbent resin and method for producing same
- Patent Title (中): 聚丙烯酸型吸水性树脂及其制造方法
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Application No.: US13807530Application Date: 2011-06-29
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Publication No.: US09074030B2Publication Date: 2015-07-07
- Inventor: Toshihiro Takaai , Hidenori Wada , Shinichi Fujino
- Applicant: Toshihiro Takaai , Hidenori Wada , Shinichi Fujino
- Applicant Address: JP Osaka
- Assignee: Nippon Shokubai Co., Ltd.
- Current Assignee: Nippon Shokubai Co., Ltd.
- Current Assignee Address: JP Osaka
- Agency: Cesari and McKenna, LLP
- Priority: JP2010-149907 20100630
- International Application: PCT/JP2011/064951 WO 20110629
- International Announcement: WO2012/002455 WO 20120105
- Main IPC: C08F20/00
- IPC: C08F20/00 ; C08J9/20 ; A61L15/24 ; A61L15/60 ; C08F220/06 ; C08J3/24 ; C08J9/36 ; C08F2/01

Abstract:
Provided is a method for producing a water absorbent resin, which promotes the formation of interconnected voids (continuous gas bubbles) in a foamed polymer (foam-like water absorbent resin) by a more convenient method, and produces with high efficiency a water absorbent resin which exhibits a high water absorption rate even when stepped into a sheet form or a powder form in hygiene articles and the like. Disclosed is a a method for producing a polyacrylic acid-type water absorbent resin, comprising (A) a step of obtaining an aqueous solution of acrylic acid-type monomers containing gas bubbles dispersed therein; (B) a step of polymerizing the aqueous monomer solution and thereby obtaining a foamed polymer; and (C) a step of heating and drying the foamed polymer, wherein gas bubbles are incorporated such that the volumetric expansion factor defined by the following formula (1); [Formula 1] Volumetric expansion factor=(Volume of aqueous monomer solution after gas bubble dispersion)/(volume of aqueous mononer solution before gas bubble dispersion) Formula (1); exceeds 1.1 times, and the aqueous monomer solution having a monomer concentration defined by the following formula (2); [Formula 2] Monomer concentration [wt %]=(Weight of a monomer)/{(weight of a monomer)+(weight of solvent)}×100 Formula (2); of 40% by weight or greater is boiling polymerized at a temperature of 100° C. or higher.
Public/Granted literature
- US20130101851A1 POLYACRYLIC ACID-TYPE WATER ABSORBENT RESIN AND METHOD FOR PRODUCING SAME Public/Granted day:2013-04-25
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