Invention Grant
US09096711B2 Powder coating composition comprising a polyester and a crosslinker with oxirane groups providing improved corrosion resistance to a substrate coated therewith
有权
粉末涂料组合物,其包含聚酯和具有环氧乙烷基团的交联剂,其对涂覆的基材提供改善的耐腐蚀性
- Patent Title: Powder coating composition comprising a polyester and a crosslinker with oxirane groups providing improved corrosion resistance to a substrate coated therewith
- Patent Title (中): 粉末涂料组合物,其包含聚酯和具有环氧乙烷基团的交联剂,其对涂覆的基材提供改善的耐腐蚀性
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Application No.: US13266530Application Date: 2010-04-28
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Publication No.: US09096711B2Publication Date: 2015-08-04
- Inventor: Paulus Franciscus Anna Buijsen , Juul Cuijpers , Marcellinus Hermanus Johannes Schutte , Johannes Albertus Hettinga
- Applicant: Paulus Franciscus Anna Buijsen , Juul Cuijpers , Marcellinus Hermanus Johannes Schutte , Johannes Albertus Hettinga
- Applicant Address: NL Heerlen
- Assignee: DSM IP ASSETS B.V.
- Current Assignee: DSM IP ASSETS B.V.
- Current Assignee Address: NL Heerlen
- Agency: Nixon & Vanderhye P.C.
- Priority: EP09159053 20090429
- International Application: PCT/EP2010/055719 WO 20100428
- International Announcement: WO2010/125105 WO 20101104
- Main IPC: C08G63/16
- IPC: C08G63/16 ; C08G63/181 ; C08G63/183 ; C08G63/20 ; C08G63/21 ; C08G63/52 ; C08K5/17 ; C08K5/1515 ; C08K5/49 ; C08K5/50 ; C08L67/02 ; C08L67/03 ; C08L67/08 ; C09D5/03 ; C09D167/02 ; C09D167/03 ; C09D167/08 ; C08K5/00 ; C08K5/19

Abstract:
The invention relates to a carboxylic acid functional branched polyester for thermosetting powder coating composition, wherein said polyester is prepared from at least the following monomers: a difunctional aromatic acid, the difunctional aromatic acid being a combination of terephthalic acid (TPA), isophthalic acid (IPA), an at least trifunctional monomer and a difunctional alcohol, the difunctional alcohol being a combination of at least ethylene glycol (EG) and/or diethylene glycol (DEG) and neopentyl glycol (NPG), the molar ratio of TPA to IPA in the carboxylic acid functional branched polyester is at most 12.4, and the functionality of the carboxylic acid functional branched polyester is from 2.15 to 4.0, and the carboxylic acid functional branched polyester has an acid value of from 14 to 80 mg KOH/g resin, and the carboxylic acid functional branched polyester has a glass transition temperature of at least 40C. The powder coating compositions of the present invention derived upon curing of the thermosetting powder coating compositions which comprise the polyester according to the invention together with a crosslinker with oxirane groups and an epoxy cure catalyst present good corrosion resistance to steel substrates. Furthermore, said low cost and corrosion resistant powder coatings may present good reverse impact resistance (RIR) and/or good smoothness.
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