The present invention relates to a wireless communication system, a communication control method, and a relay station. The wireless communication system includes: a wireless terminal; a plurality of base stations; and a relay station, wherein the relay station defines a wirelessly communicable base station among the plurality of base stations as a candidate for a master station, in a case where a plurality of the candidates for the master station are present, acquires priority order setting information for setting priority orders of connection regarding the respective candidates for the master station, and sets the priority orders of the connection based on the priority order setting information. Then, in a case where the relay station has received a connection request from the wireless terminal, the control unit decides a candidate for the master station, which has a highest priority order of the connection, as an optimal master station.