Invention Grant
- Patent Title: Modified zeolite catalyst
- Patent Title (中): 改性沸石催化剂
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Application No.: US13377725Application Date: 2010-06-22
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Publication No.: US09120090B2Publication Date: 2015-09-01
- Inventor: Avelino Corma , Cristina Martinez , Eric J. Doskocil , George Yaluris
- Applicant: Avelino Corma , Cristina Martinez , Eric J. Doskocil , George Yaluris
- Applicant Address: GB Sunbury on Thames US TX Houston
- Assignee: BP Oil International Limited,BP Corporation North America Inc.
- Current Assignee: BP Oil International Limited,BP Corporation North America Inc.
- Current Assignee Address: GB Sunbury on Thames US TX Houston
- Agent Kelly L. Cummings; Ekkehard Schoettle
- Priority: EP09380129 20090703
- International Application: PCT/US2010/039407 WO 20100622
- International Announcement: WO2011/002630 WO 20110106
- Main IPC: B01J29/06
- IPC: B01J29/06 ; B01J35/10 ; B01J29/44 ; B01J29/70 ; B01J29/72 ; B01J29/78 ; B01J37/06 ; C01B39/02 ; C07C1/20 ; C10G50/00

Abstract:
A modified zeolite catalyst derived from a zeolite of a structural type which consists of a one-dimensional micropore structure of channels made from rings containing between 8 and 12 silicon/aluminum atoms is disclosed. It consists substantially of a plurality of crystallites having additional mesoporosity whose volume is in the range 0.09 to 0.25 cc/g as mentioned by nitrogen adsorption at 77° K and calculated by the BJH method. The mesoporosity may be introduced into the crystallites by e.g. treatment with aqueous sodium hydroxide at a pH at 25° C. in excess of 8 for an extended period at elevated temperature. The catalyst shows improved resistance to catalyst deactivation and greater selectivity to higher hydrocarbons when used to e.g. oligomerize light alkenes e.g. propene or the butenes.
Public/Granted literature
- US20120178615A1 Modified Zeolite Catalyst Public/Granted day:2012-07-12
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