Invention Grant
- Patent Title: Method for doping and dedoping lithium into and from negative electrode and method for producing negative electrode for lithium secondary battery
- Patent Title (中): 从负极中掺杂和去掺杂锂的方法和用于生产锂二次电池的负极的方法
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Application No.: US14114948Application Date: 2012-04-06
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Publication No.: US09123928B2Publication Date: 2015-09-01
- Inventor: Jiro Iriyama , Tetsuya Kajita , Daisuke Kawasaki , Tatsuji Numata
- Applicant: Jiro Iriyama , Tetsuya Kajita , Daisuke Kawasaki , Tatsuji Numata
- Applicant Address: JP Tokyo
- Assignee: NEC Corporation
- Current Assignee: NEC Corporation
- Current Assignee Address: JP Tokyo
- Agency: Finnegan, Henderson, Farabow, Garrett & Dunner LLP
- Priority: JP2011-119232 20110527
- International Application: PCT/JP2012/059540 WO 20120406
- International Announcement: WO2012/165049 WO 20121206
- Main IPC: H01M4/04
- IPC: H01M4/04 ; H01M4/134 ; H01M4/1395 ; H01M4/485

Abstract:
The object of an exemplary embodiment of the invention is to provide a negative electrode having excellent cycle property. An exemplary embodiment of the invention a method for doping and dedoping lithium for the first time after a negative electrode for a lithium secondary battery comprising silicon oxide as an active material is produced, comprising doping the lithium within the following current value range (A) and within the following doped amount range (B); current value range (A): a range of a current value in which a doped amount in which only one peak appears at 1 V or less on the V-dQ/dV curve becomes maximum, wherein the V-dQ/dV curve represents a relationship between voltage V of the negative electrode with respect to a lithium reference electrode and dQ/dV that is a ratio of variation dQ of lithium dedoped amount Q in the negative electrode to variation dV of the voltage V, and doped amount range (B): a range of a doped amount in which only one peak appears at 1 V or less on the V-dQ/dV curve.
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