A liquid crystal lens, a manufacturing method thereof, an operation method thereof and a photoelectric device are provided. The lens comprises: a first electrode layer; a first transparent substrate; a second transparent substrate, provided to a lower surface of the first electrode layer and opposite to the first transparent substrate; a second electrode layer, provided to an upper surface of the first transparent substrate and comprising a first sub-electrode-layer and a second sub-electrode-layer which are separated from each other; and a liquid crystal layer provided between the second transparent substrate and the second electrode layer.