A docking station includes a docking body and a hinge structure. The docking body includes a casing having an articulated portion and an operation interface disposed at the casing. The hinge structure is connected with the docking body vertiginously and includes a hinge assembly and a pivot portion. The hinge assembly includes a pivot, a fixed rack, a rotating rack, a first positioning cam set and a second positioning cam set. The pivot is connected with the pivot portion, while the pivot portion is articulated with the articulated portion. One end of the pivot is connected with the fixed rack. The fixed rack is connected with the docking body. The rotating rack is rotatable relative to the fixed rack and has a first spacing angle by the first positioning cam set and a second spacing angle by the second positioning cam set.