A data capturing method of near-field communication (NFC) protocol and an NFC electronic device thereof are provided. The method can be applied to an NFC electronic device with an operation system, and the operation system includes a kernel mode and a user mode. The method includes following steps: detecting a readable element by an interface drive module in the kernel mode to obtain NFC original data transferred by the readable element; capturing the NFC original data from the interface drive module by a capturing module and outputting the NFC original data to an analyzing module in the user mode; and analyzing the NFC original data by the analyzing module to obtain NFC target data.