Invention Grant
- Patent Title: Method for producing cycloolefin and production apparatus thereof
- Patent Title (中): 环烯烃的制造方法及其制造装置
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Application No.: US13055103Application Date: 2009-06-12
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Publication No.: US09174894B2Publication Date: 2015-11-03
- Inventor: Mitsuo Konishi
- Applicant: Mitsuo Konishi
- Applicant Address: JP Tokyo
- Assignee: ASAHI KASEI CHEMICALS CORPORATION
- Current Assignee: ASAHI KASEI CHEMICALS CORPORATION
- Current Assignee Address: JP Tokyo
- Agency: Finnegan, Henderson, Farabow, Garrett & Dunner, L.L.P.
- Priority: JP2008-196265 20080730
- International Application: PCT/JP2009/060761 WO 20090612
- International Announcement: WO2010/013548 WO 20100402
- Main IPC: C07C5/11
- IPC: C07C5/11 ; B01J8/00 ; B01J23/96 ; B01J38/70 ; B01J23/46

Abstract:
There is provided a method for producing cycloolefin where the nickel which elutes in the liquid-contact portion of the reactor is removed from the reaction system of the partial hydrogenation reaction and cycloolefin can be stably produced from a monocyclic aromatic hydrocarbon over a long term. A method for producing a cycloolefin by a partial hydrogenation reaction of a monocyclic aromatic hydrocarbon in an aqueous phase, which contains a metal salt-containing acidic aqueous solution and a ruthenium catalyst in a reactor with a liquid-contact portion formed of a nickel-containing material, the method comprising a first step of bringing at least a part of the ruthenium catalyst contained in the aqueous phase into contact with oxygen, a second step of separating the aqueous phase containing the ruthenium catalyst that has been processed in the first step into a first phase containing the ruthenium catalyst at a high ratio and a second phase containing the ruthenium catalyst at a lower ratio than the first phase, and a third step of feeding the first phase to a reaction system of a partial hydrogenation reaction.
Public/Granted literature
- US20110130600A1 METHOD FOR PRODUCING CYCLOOLEFIN AND PRODUCTION APPARATUS THEREOF Public/Granted day:2011-06-02
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