Invention Grant
- Patent Title: Manufacture of an epoxyethyl carboxylate or glycidyl carboxylate
- Patent Title (中): 环氧乙基羧酸酯或羧酸缩水甘油酯的制备
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Application No.: US13574693Application Date: 2011-01-26
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Publication No.: US09174955B2Publication Date: 2015-11-03
- Inventor: Prasad Muppa , Ron Postma , Caspar Schoolderman , Sandra Rens , Kostas Stoitsas
- Applicant: Prasad Muppa , Ron Postma , Caspar Schoolderman , Sandra Rens , Kostas Stoitsas
- Applicant Address: US OH Columbus
- Assignee: HEXION INC.
- Current Assignee: HEXION INC.
- Current Assignee Address: US OH Columbus
- Priority: EP10001034 20100202
- International Application: PCT/EP2011/000322 WO 20110126
- International Announcement: WO2011/095294 WO 20110811
- Main IPC: C07D303/12
- IPC: C07D303/12 ; C07D301/12 ; C07D303/48

Abstract:
The invention relates to a process for the manufacture of an epoxyethyl carboxylate or glycidyl carboxylate, including reacting a vinyl carboxylate or an allyl carboxylate using an oxidant and a water-soluble manganese complex in an aqueous reaction medium, and the water-soluble manganese complex comprises an oxidation catalyst, characterized in that the water-soluble manganese complex is a mononuclear species of the general formula (I) [LMnX3]Y (I), or a binuclear species of the general formula (II): [LMn(μ-X)3MnL]Yn (II), wherein Mn is a manganese; L is a ligand and each L is independently a polydentate ligand, each X is independently a coordinating species and each μ-X is independently a bridging coordinating species, Y is a non-coordinating counter ion, and wherein the epoxidation is carried out at a pH in the range of from 1.0 to 7.0.
Public/Granted literature
- US20130006001A1 MANUFACTURE OF AN EPOXYETHYL CARBOXYLATE OR GLYCIDYL CARBOXYLATE Public/Granted day:2013-01-03
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