Invention Grant
US09231217B2 Synthesis method of organometallic complex, synthesis method of pyrazine derivative, 5,6-diaryl-2-pyrazyl triflate, light-emitting element, light-emitting device, electronic device, and lighting device
有权
有机金属配合物的合成方法,吡嗪衍生物的合成方法,三氟甲磺酸5,6-二芳基-2-吡唑酯,发光元件,发光元件,电子器件及照明装置
- Patent Title: Synthesis method of organometallic complex, synthesis method of pyrazine derivative, 5,6-diaryl-2-pyrazyl triflate, light-emitting element, light-emitting device, electronic device, and lighting device
- Patent Title (中): 有机金属配合物的合成方法,吡嗪衍生物的合成方法,三氟甲磺酸5,6-二芳基-2-吡唑酯,发光元件,发光元件,电子器件及照明装置
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Application No.: US14551712Application Date: 2014-11-24
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Publication No.: US09231217B2Publication Date: 2016-01-05
- Inventor: Hideko Inoue , Tomohiro Kubota , Miki Kanamoto
- Applicant: Semiconductor Energy Laboratory Co., Ltd.
- Applicant Address: JP
- Assignee: Semiconductor Energy Laboratory Co., Ltd.
- Current Assignee: Semiconductor Energy Laboratory Co., Ltd.
- Current Assignee Address: JP
- Agency: Husch Blackwell LLP
- Priority: JP2013-245957 20131128
- Main IPC: H01L21/76
- IPC: H01L21/76 ; H01L51/00 ; C07F15/00 ; C07D241/12 ; C09K11/06 ; H01L51/50

Abstract:
Provided is a 5,6-diaryl-2-pyrazyl triflate, its synthetic method, and a method for synthesizing an organometallic complex having a triarylpyrazine ligand from the 5,6-diaryl-2-pyrazyl triflate. The triflate is readily obtained from the corresponding 5,6-diarylpyrazin-2-ol, and the palladium-catalyzed coupling of the 5,6-diaryl-2-pyrazyl triflate with an arylboronic acid derivative leads to a high yield of a triarylpyrazine derivative having high purity. The use of the triarylpyrazine derivative in the reaction with a metal compound such as a metal chloride results in an ortho-metallated organometallic complex with high purity. The high purity of the organometallic complex contributes to the extremely high durability of a light-emitting element.
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