A method for manufacturing a carbon fiber rim is disclosed, which includes: preparing a carbon fiber composite material and a thermosetting resin-based composite material; preparing a mold to place the carbon fiber composite material into the mold so that the carbon fiber composite material forms a pre-molded rim according to the shape of the mold, and then annularly affixing the thermosetting resin-based composite material respectively to brake surfaces on both sides of the pre-molded rim, so as to form a brake layer; placing the pre-molded rim into the mold to integrally form a rim by means of heat and pressure; and taking out the rim having the brake layer on the surface.