Invention Grant
- Patent Title: Process for polymerizing or copolymerizing ethylenically unsaturated monomers in the presence of free-radical polymerization initiators
- Patent Title (中): 在自由基聚合引发剂存在下聚合或共聚烯属不饱和单体的方法
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Application No.: US14355512Application Date: 2012-11-01
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Publication No.: US09243082B2Publication Date: 2016-01-26
- Inventor: Klaus Berhalter , Andrei Gonioukh , Thomas Herrmann , David Finotto , Gilles Rieu , Laurent Hautier , Christoph Treis
- Applicant: Basell Polyolefine GmbH
- Applicant Address: DE Wesseling
- Assignee: Basell Polyolefine GmbH
- Current Assignee: Basell Polyolefine GmbH
- Current Assignee Address: DE Wesseling
- Priority: EP11187690 20121103
- International Application: PCT/EP2012/071644 WO 20121101
- International Announcement: WO2013/064586 WO 20130510
- Main IPC: C08F2/00
- IPC: C08F2/00 ; C08F2/34 ; C08F4/04 ; C08F4/34 ; C08F10/02 ; C08F10/00 ; C08F2/38

Abstract:
Process for polymerizing or copolymerizing ethylenically unsaturated monomers in the presence of free-radical polymerization initiators at pressures in the range of from 110 MPa to 500 MPa and temperatures in the range of from 100° C. to 350° C. in a continuously operated polymerization apparatus, wherein the reaction gas composition is compressed to the polymerization pressure by at least two sequentially operating compressors in which a low-pressure compressor first compresses the reaction gas composition to a pressure of from 10 MPa to 50 MPa and a high-pressure compressor then further compresses the reaction gas composition to the polymerization pressure wherein the high-pressure compressor is operated with a polyalkylene glycol based synthetic lubricant and oxygen is introduced into the fresh gas feed or into the polymerization apparatus in an amount that the gas composition to be compressed in the high-pressure compressor has an oxygen content in the range of from 0.01 ppm to 0.9 ppm.
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