Invention Grant
- Patent Title: Method for continuous production of high molecular weight polycarbonate resin
- Patent Title (中): 连续生产高分子量聚碳酸酯树脂的方法
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Application No.: US14400640Application Date: 2013-05-14
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Publication No.: US09243106B2Publication Date: 2016-01-26
- Inventor: Yoshinori Isahaya , Atsushi Hirashima , Hidefumi Harada , Maki Ito , Jun-ya Hayakawa , Takehiko Isobe , Taichi Tokutake , Yousuke Shinkai
- Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.
- Applicant Address: JP Tokyo
- Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
- Current Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
- Current Assignee Address: JP Tokyo
- Agency: Greenblum & Bernstein, P.L.C.
- Priority: JP2012-114936 20120518
- International Application: PCT/JP2013/063345 WO 20130514
- International Announcement: WO2013/172317 WO 20131121
- Main IPC: C08G64/00
- IPC: C08G64/00 ; C08G64/30 ; C08G64/16 ; C08G64/06 ; C08G63/02

Abstract:
A high molecular weight polycarbonate resin is continuously produced by subjecting an aromatic polycarbonate prepolymer and an aliphatic diol compound to a linking and highly polymerizing reaction. Even an aliphatic diol compound having a comparatively low boiling point can be allowed to efficiently contribute to the linking and highly polymerizing reaction. An aromatic polycarbonate prepolymer is produced by a polycondensation reaction between an aromatic dihydroxy compound and a diester carbonate, adding an aliphatic diol compound having an aliphatic group bonding to a terminal hydroxyl group to obtain a prepolymer mixture, and subjecting the resulting prepolymer mixture to a linking and highly polymerizing reaction under reduced pressure. The aliphatic diol compound is added at a pressure exceeding 200 torr, and the prepolymer mixture is subjected to a linking and highly polymerizing reaction before the terminal hydroxyl group concentration of the aromatic polycarbonate prepolymer in the prepolymer mixture reaches 2000 ppm.
Public/Granted literature
- US20150133611A1 METHOD FOR CONTINUOUS PRODUCTION OF HIGH MOLECULAR WEIGHT POLYCARBONATE RESIN Public/Granted day:2015-05-14
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