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US09249068B2 Process for the production of xylenes 有权
生产二甲苯的方法

Process for the production of xylenes
Abstract:
In a process for producing para-xylene, a feed stream comprising C6+ aromatic hydrocarbons is separated into a C7− aromatic hydrocarbon-containing stream, a C8 aromatic hydrocarbon-containing stream, and a C9+ aromatic hydrocarbon-containing stream. The C7− aromatic hydrocarbon-containing stream is contacted with a methylating agent to convert toluene to xylenes and produce a methylated effluent stream. Ethylbenzene is removed from the C8 aromatic hydrocarbon-containing stream, para-xylene is recovered from the ethylbenzene-depleted C8 aromatic hydrocarbon-containing stream and the methylated effluent stream in a para-xylene recovery section to produce a para-xylene depleted stream, which is then contacted with a xylene isomerization catalyst under liquid phase conditions effective to isomerize xylenes in the para-xylene depleted stream and produce an isomerized stream. The C9+-containing stream with a transalkylation catalyst under conditions effective to convert C9+-aromatics to C8−-aromatics and produce a transalkylated stream, which is recycled together with the isomerized stream to the para-xylene recovery section.
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