Invention Grant
US09249238B2 Reversible chain-transfer in polyolefin polymerization with pyridyldiamide catalysts
有权
使用吡啶基二酰胺催化剂进行聚烯烃聚合中的可逆链转移
- Patent Title: Reversible chain-transfer in polyolefin polymerization with pyridyldiamide catalysts
- Patent Title (中): 使用吡啶基二酰胺催化剂进行聚烯烃聚合中的可逆链转移
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Application No.: US14195634Application Date: 2014-03-03
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Publication No.: US09249238B2Publication Date: 2016-02-02
- Inventor: John R. Hagadorn , Jian Yang , Patrick J. Palafox
- Applicant: ExxonMobil Chemical Patents Inc.
- Applicant Address: US TX Baytown
- Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee Address: US TX Baytown
- Main IPC: C08F4/76
- IPC: C08F4/76 ; C08F4/50 ; C08F4/52 ; C08F297/08 ; C08F4/64 ; C08F4/62

Abstract:
A process of producing ethylene α-olefin copolymers, especially ethylene block copolymers, comprising contacting ethylene and a C3 to C10 α-olefin with a transition metal pyridyldiamide (MPN3) catalyst component and an activator, as well as from 10 equivalents to 1000 equivalents relative to the catalyst component of chain transfer agent; isolating an ethylene-α-olefin copolymer having a Tm of less than 140° C., a MWD of less than 2.5, and a weight average molecular weight (Mw) within the range of from 5 kDa to 500 kDa. The chain transfer agent can be selected from Group 2, 12 or Group 13 alkyl or aryl compounds.
Public/Granted literature
- US20140256893A1 Reversible Chain-Transfer in Polyolefin Polymerization With Pyridyldiamide Catalysts Public/Granted day:2014-09-11
Information query
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