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US09249238B2 Reversible chain-transfer in polyolefin polymerization with pyridyldiamide catalysts 有权
使用吡啶基二酰胺催化剂进行聚烯烃聚合中的可逆链转移

Reversible chain-transfer in polyolefin polymerization with pyridyldiamide catalysts
Abstract:
A process of producing ethylene α-olefin copolymers, especially ethylene block copolymers, comprising contacting ethylene and a C3 to C10 α-olefin with a transition metal pyridyldiamide (MPN3) catalyst component and an activator, as well as from 10 equivalents to 1000 equivalents relative to the catalyst component of chain transfer agent; isolating an ethylene-α-olefin copolymer having a Tm of less than 140° C., a MWD of less than 2.5, and a weight average molecular weight (Mw) within the range of from 5 kDa to 500 kDa. The chain transfer agent can be selected from Group 2, 12 or Group 13 alkyl or aryl compounds.
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