Invention Grant
US09255167B2 Method of making diarlysilanediol containing polymers, polymer compositions and articles containing such polymers
有权
制备含二聚硅烷二醇的聚合物,聚合物组合物和含有这种聚合物的制品的方法
- Patent Title: Method of making diarlysilanediol containing polymers, polymer compositions and articles containing such polymers
- Patent Title (中): 制备含二聚硅烷二醇的聚合物,聚合物组合物和含有这种聚合物的制品的方法
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Application No.: US14560651Application Date: 2014-12-04
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Publication No.: US09255167B2Publication Date: 2016-02-09
- Inventor: James H. Pawlow , Mark N. DeDecker
- Applicant: Firestone Polymers, LLC
- Applicant Address: US OH Akron
- Assignee: Firestone Polymers, LLC
- Current Assignee: Firestone Polymers, LLC
- Current Assignee Address: US OH Akron
- Agent Meredith E. Hooker; Harry J. Gwinnell
- Main IPC: C08F236/10
- IPC: C08F236/10 ; C08L9/06

Abstract:
A method of making a polymer with stable Mooney viscosity and molecular weight is described. A conjugated diolefin is reacted in a hydrocarbon solvent in the presence of an initiator to form a polymer. After forming the polymer, alkoxy silane terminal functionalizing groups are bonded to the polymer. A mixture of at least one of a first stabilizing agent having the formula (R)4-nSi(OH)n wherein R is a C1 to C18 alkyl, C1 to C18 alkyl group containing a heteroatom such as nitrogen or oxygen, C4 to C8 cycloalkyl, or C6 to C18 aromatic group, and a at least one of a second stabilizing agents having the formula (R)2Si(OH)2 wherein R is an aryl group, is then added to the polymer, optionally in the presence of hydrocarbon oil. The polymer is then desolvatized, resulting in a polymer with stable Mooney viscosity and molecular weight, even over prolonged periods of time. Compositions and articles containing the polymer are also described.
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