Invention Grant
US09255167B2 Method of making diarlysilanediol containing polymers, polymer compositions and articles containing such polymers 有权
制备含二聚硅烷二醇的聚合物,聚合物组合物和含有这种聚合物的制品的方法

  • Patent Title: Method of making diarlysilanediol containing polymers, polymer compositions and articles containing such polymers
  • Patent Title (中): 制备含二聚硅烷二醇的聚合物,聚合物组合物和含有这种聚合物的制品的方法
  • Application No.: US14560651
    Application Date: 2014-12-04
  • Publication No.: US09255167B2
    Publication Date: 2016-02-09
  • Inventor: James H. PawlowMark N. DeDecker
  • Applicant: Firestone Polymers, LLC
  • Applicant Address: US OH Akron
  • Assignee: Firestone Polymers, LLC
  • Current Assignee: Firestone Polymers, LLC
  • Current Assignee Address: US OH Akron
  • Agent Meredith E. Hooker; Harry J. Gwinnell
  • Main IPC: C08F236/10
  • IPC: C08F236/10 C08L9/06
Method of making diarlysilanediol containing polymers, polymer compositions and articles containing such polymers
Abstract:
A method of making a polymer with stable Mooney viscosity and molecular weight is described. A conjugated diolefin is reacted in a hydrocarbon solvent in the presence of an initiator to form a polymer. After forming the polymer, alkoxy silane terminal functionalizing groups are bonded to the polymer. A mixture of at least one of a first stabilizing agent having the formula (R)4-nSi(OH)n wherein R is a C1 to C18 alkyl, C1 to C18 alkyl group containing a heteroatom such as nitrogen or oxygen, C4 to C8 cycloalkyl, or C6 to C18 aromatic group, and a at least one of a second stabilizing agents having the formula (R)2Si(OH)2 wherein R is an aryl group, is then added to the polymer, optionally in the presence of hydrocarbon oil. The polymer is then desolvatized, resulting in a polymer with stable Mooney viscosity and molecular weight, even over prolonged periods of time. Compositions and articles containing the polymer are also described.
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