Invention Grant
- Patent Title: Stable long-term method for producing C5-aldehydes
- Patent Title (中): 稳定的长久生产C5醛的方法
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Application No.: US14435052Application Date: 2013-09-27
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Publication No.: US09272973B2Publication Date: 2016-03-01
- Inventor: Dirk Fridag , Robert Franke , Dieter Hess , Markus Schwarz , Katrin Marie Dyballa , Hans-Gerd Lueken , Bart Hamers , Uwe Ernst
- Applicant: Dirk Fridag , Robert Franke , Dieter Hess , Markus Schwarz , Katrin Marie Dyballa , Hans-Gerd Lueken , Bart Hamers , Uwe Ernst
- Applicant Address: DE Essen
- Assignee: Evonik Industries AG
- Current Assignee: Evonik Industries AG
- Current Assignee Address: DE Essen
- Agency: Oblon, McClelland, Maier & Neustadt, L.L.P.
- Priority: DE102012218625 20121012; DE102012218627 20121012; DE102012218629 20121012; DE102012218630 20121012
- International Application: PCT/EP2013/070208 WO 20130927
- International Announcement: WO2014/056732 WO 20140417
- Main IPC: C07C45/50
- IPC: C07C45/50 ; B01J31/18 ; C07F9/6574 ; B01J31/02 ; B01J19/24 ; C07C67/38 ; C07F9/6568

Abstract:
The invention relates to a process for preparing aldehydes having five carbon atoms, in which an input mixture containing 10% by weight to 50% by weight of linear butenes and less than 5% by weight of 1-butene is hydroformylated with synthesis gas in the presence of a catalyst system comprising rhodium and at least one bisphosphite ligand, wherein the hydroformylation is effected in a reactor from which, over an operating period, a cycle gas containing at least a portion of the products and unconverted reactants from the hydroformylation is continuously drawn off and partly condensed, and uncondensed components of the cycle gas are recycled into the reactor, and wherein, after the operating period has expired, the hydroformylation is stopped, the reactor is freed of reaction residues and the hydroformylation is restarted. It is based on the problem of making such a process more economically viable. The problem is solved by using a bisphosphite of the formula (1) and/or (2) as ligand, extending the operating period to more than 8000 h, and not separating solid reaction residues out of the reactor during the course of the operating period.
Public/Granted literature
- US20150224488A1 STABLE LONG-TERM METHOD FOR PRODUCING C5-ALDEHYDES Public/Granted day:2015-08-13
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