Invention Grant
US09278899B2 Method for producing 3,5-dimethyldodecanoic acid; and 4-carboxy-3,5-Dimethyl-3,5-dodecadienoic acid
有权
3,5-二甲基十二烷酸的制备方法 和4-羧基-3,5-二甲基-3,5-二十二碳烯酸
- Patent Title: Method for producing 3,5-dimethyldodecanoic acid; and 4-carboxy-3,5-Dimethyl-3,5-dodecadienoic acid
- Patent Title (中): 3,5-二甲基十二烷酸的制备方法 和4-羧基-3,5-二甲基-3,5-二十二碳烯酸
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Application No.: US14713582Application Date: 2015-05-15
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Publication No.: US09278899B2Publication Date: 2016-03-08
- Inventor: Akihiro Baba , Takeshi Kinsho , Naoki Ishibashi
- Applicant: Shin-Etsu Chemical Co., Ltd.
- Applicant Address: JP
- Assignee: Shin-Etsu Chemical Co., Ltd.
- Current Assignee: Shin-Etsu Chemical Co., Ltd.
- Current Assignee Address: JP
- Agency: Myers Bigel Sibley & Sajovec
- Priority: JP2014-109166 20140527
- Main IPC: C07C51/36
- IPC: C07C51/36 ; C07C51/373 ; C07C51/09 ; C07C51/38 ; C07C57/13

Abstract:
Provided is a process for producing 3,5-dimethyldodecanoic acid, which is an active ingredient of the pheromone of California prionus, and 4-carboxy-3,5-dimethyl-3,5-dodecadienoic acid which is an intermediate useful for producing 3,5-dimethyldodecanoic acid. More specifically, provided is a method for producing 3,5-dimethyldodecanoic acid, comprising the steps of subjecting 3-methyl-2-pentene-1,5-diacid diester (1) and 2-nonanone (2) to a condensation reaction and subsequent hydrolysis into 4-carboxy-3,5-dimethyl-3,5-dodecadienoic acid (3); decarboxylating or decarboxylating and hydrolyzing the 4-carboxy-3,5-dimethyl-3,5-dodecadienoic acid (3) into 3,5-dimethyl-2,4-dodecadienoic acid (4); and hydrogenating the 3,5-dimethyl-2,4-dodecadienoic acid (4) into 3,5-dimethyldodecanoic acid (5), as shown in the following scheme:
Public/Granted literature
- US20150344395A1 METHOD FOR PRODUCING 3,5-DIMETHYLDODECANOIC ACID; AND 4-CARBOXY-3,5-DIMETHYL-3,5-DODECADIENOIC ACID Public/Granted day:2015-12-03
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