A pixel array, a pixel structure, and a driving method of a pixel structure are provided. The pixel structure includes a first scan line, a second scan line, a first common electrode line, a data line, a first active device, a second device, a first pixel electrode, and a second pixel electrode. The data line is intersected with the first scan line and the second scan line. The first active device is driven by the first scan line and connected to the data line. The second active device is driven by the second scan line and connected to the first common electrode line. The first pixel electrode is electrically connected to the data line through the first active device. The second pixel electrode is electrically connected to the data line through the first active device and electrically connected to the first common electrode line through the second active device.