Invention Grant
US09334349B2 Polyolefin polymerization process, semi-crystalline ethylene-based polymer made therefrom, and articles made from the polymer
有权
聚烯烃聚合方法,由其制成的半结晶乙烯类聚合物和由聚合物制成的制品
- Patent Title: Polyolefin polymerization process, semi-crystalline ethylene-based polymer made therefrom, and articles made from the polymer
- Patent Title (中): 聚烯烃聚合方法,由其制成的半结晶乙烯类聚合物和由聚合物制成的制品
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Application No.: US14394492Application Date: 2013-03-14
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Publication No.: US09334349B2Publication Date: 2016-05-10
- Inventor: Ludovicus J C Sluijts , Armanda Van Putten , Ian M. Munro
- Applicant: Dow Global Technologies LLC
- Applicant Address: US MI Midland
- Assignee: Dow Global Technologies LLC
- Current Assignee: Dow Global Technologies LLC
- Current Assignee Address: US MI Midland
- International Application: PCT/US2013/031190 WO 20130314
- International Announcement: WO2013/169359 WO 20131114
- Main IPC: C08F4/64
- IPC: C08F4/64 ; C08F210/16 ; C08F4/642

Abstract:
A polymerization process comprising (A) polymerizing ethylene in the presence of a catalyst to form a semi-crystalline ethylene-based polymer in at least one reactor; the catalyst comprising an organometallic catalyst thereby forming an ethylene-based polymer composition in the at least one reactor, wherein the catalyst is a metal complex of a polyvalent aryloxyether corresponding to the formula: wherein step (A) is conducted in the presence of from 5 to 20 mmol/m3 triethylaluminum; and wherein step (A) is conducted in the presence of one or both of the following conditions: (i) from greater than 0:1 to 65:1 molar ratio of triethylaluminum to the catalyst; and (ii) from 0.1:0 to 5:1 molar ratio of triethylaluminum to modified methylalumoxane is provided.
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