Invention Grant
- Patent Title: Method for preparing refractory alloy-based polymetallic oxide catalysts for the partial oxidation of hydrocarbons into synthesis gas
- Patent Title (中): 制备用于将烃部分氧化成合成气的耐火合金基多金属氧化物催化剂的方法
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Application No.: US14769021Application Date: 2013-12-02
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Publication No.: US09346039B2Publication Date: 2016-05-24
- Inventor: Sergey Erikovich Dolinskiy , Nikolay Yakovlevich Usachev , Andrey Mikhaylovich Pleshakov
- Applicant: OBSHCHESTVO S OGRANICHENNOY OTVETSTVENNOST'YU “GAZOKHIM TEKHNO”
- Applicant Address: RU Moskovskaya OBL.
- Assignee: OBSHCHESTVO S OGRANICHENNOY OTVETSTVENNOST'YU, “GAZOKHIM TEKHNO”
- Current Assignee: OBSHCHESTVO S OGRANICHENNOY OTVETSTVENNOST'YU, “GAZOKHIM TEKHNO”
- Current Assignee Address: RU Moskovskaya OBL.
- Agency: Pequignot + Myers LLC
- Agent Matthew A. Pequignot
- Priority: RU2013151143 20131119
- International Application: PCT/RU2013/001081 WO 20131202
- International Announcement: WO2015/076696 WO 20150528
- Main IPC: B01J23/10
- IPC: B01J23/10 ; B01J23/89 ; B01J37/08 ; B01J21/04 ; B01J21/06 ; B01J23/83 ; B01J23/882 ; B01J23/883 ; B01J37/00 ; B82B3/00 ; C01B3/40 ; B01J23/86 ; B01J37/02

Abstract:
The invention relates to a method for preparation of oxide-polymetallic catalysts containing platinum-group metals for steam-oxidative conversion to obtain carbon monoxide and hydrogen. The method comprises treatment of NiO and CO3O4 by solutions of Al, Ce, Zr nitrates and palladium (Pd(NH3)4Cl2), platinum (H2[PtCl6]·6H2O) and rhodium (H3[RhCl6]) compounds followed by drying, carbonization of the obtained material in a methane flow at 550° C., preparation of slurry from this material, pseudo-boehmite and tetraisopropoxysilane, filling foam nichrome pores with obtained material suspension, elimination of water at 80° C., calcinating during 3 hours in an atmosphere of argon at 1300° C., elimination of carbon by water vapors at 600° C. during 3 hours. The technical result is development of a highly efficient heterogeneous catalyst. 3 material claims, 7 tables, 4 examples.
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