Invention Grant
- Patent Title: Continuous process of oxidative cleavage of vegetable oils
- Patent Title (中): 植物油氧化裂解的连续过程
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Application No.: US14456243Application Date: 2014-08-11
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Publication No.: US09346732B2Publication Date: 2016-05-24
- Inventor: Arno Bieser , Giampietro Borsotti , Francesca Digioia , Adriano Ferrari , Alexxandro Pirocco
- Applicant: Novamont S.p.A.
- Applicant Address: IT Novara
- Assignee: Novamont S.p.A.
- Current Assignee: Novamont S.p.A.
- Current Assignee Address: IT Novara
- Agency: Polsinelli PC
- Priority: ITMI2009A2360 20091230
- Main IPC: C07C51/16
- IPC: C07C51/16 ; C07C51/09 ; C07C51/245 ; C07C51/353

Abstract:
A continuous process for the oxidative cleavage of vegetable oils containing triglycerides of unsaturated carboxylic acids, to obtain saturated carboxylic acids, comprising feeding to a first continuous reactor a vegetable oil, an oxidizing compound and catalyst capable of catalyzing the oxidation reaction of the olefinic double bond to obtain an intermediate compound containing vicinal diols: feeding to a second continuous reactor said intermediate compound, a compound containing oxygen and a catalyst capable of catalyzing the oxidation reaction of the vicinal diols to carboxylic groups, to obtain saturated monocarboxylic acids (i) and triglycerides containing saturated carboxylic acids with more than one acid function (ii); separating the saturated monocarboxylic acids (i) from the triglycerides (ii); hydrolyzing in a third reactor the triglycerides (ii) to obtain glycerol and saturated carboxylic acids with more than one acid function; and purifying said saturated carboxylic acids by fractioned crystallization by means of wash column (melt crystallization).
Public/Granted literature
- US20150005521A1 CONTINUOUS PROCESS OF OXIDATIVE CLEAVAGE OF VEGETABLE OILS Public/Granted day:2015-01-01
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