An electrode is provided as one capable of achieving further improvement in safety of an electrochemical device when exposed to a high-temperature environment, and an electrochemical device is provided as one using the electrode. The electrode has a current collector, an endothermic material layer provided on the current collector, and an active material layer provided on the endothermic material layer. The endothermic material layer contains an endothermic material absorbing heat at 80° C. or higher in a differential scanning calorimetry curve thereof.