Invention Grant
- Patent Title: Allyl-bearing fluorinated ionomers
- Patent Title (中): 含烯丙基的氟化离聚物
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Application No.: US14420708Application Date: 2013-07-30
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Publication No.: US09434679B2Publication Date: 2016-09-06
- Inventor: Luca Merlo , Vito Tortelli , Ivan Wlassics , Claudio Oldani
- Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
- Applicant Address: IT Bollate (Milano)
- Assignee: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
- Current Assignee: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
- Current Assignee Address: IT Bollate (Milano)
- Priority: EP12180024 20120810
- International Application: PCT/EP2013/065980 WO 20130730
- International Announcement: WO2014/023611 WO 20140213
- Main IPC: C07C217/46
- IPC: C07C217/46 ; C07C41/30 ; C07C213/02 ; C07C43/17 ; C08J5/22 ; C08G65/00 ; C08F216/14

Abstract:
The present invention provides a fluorinated ionomer [polymer (I)] comprising recurring units derived from at least the following monomers: (i) 5 to 50% by weight of a fluorinated monomer [monomer (A)] containing at least one —SO2X functionality, preferably having the formula of CF2═CF—O—(CF2CF(CF3)O)m—(CF2)mSO2X (I) wherein m is 0 or 1, n is an integer between 0-10, and X is selected from F, OH, and O−Me+, wherein Me+ indicates an alkali metal ion or an ammonium cation of formula NR4− where each R independently represents a hydrogen atom or a monovalent organic radical selected from aliphatic radicals having from 1 to 8 carbon atoms and arylic or alicyclic radicals having from 3 to 8 carbon atoms; (ii) a non-functional fluorinated monomer [monomer (B)] having at least one ethylene unsaturation; and (iii) a fluorinated polyfunctional compound having the general formula: (CR1R2═CFCF2—O)a—Rf—((O)c—CF═CR3R4)b (II) wherein: a is an integer equal to or larger than 1, preferably a is 1, 2, or 3; b is 0 or 1 and the sum of a and b is an integer equal to or larger than 2; c is 0 or 1; R1, R2, R3 and R4 are independently selected from F, H, alkyl, alkoxy, polyoxy alkyl, perfluoroalkyl, perfluoroalkoxy or perfluoropolyoxy alkyl, preferably F; and Rf represents a hydrocarbon or fluorocarbon group having at least two carbon atoms. The low-EW perfluorinated ionomers made of polymer (I) are adapted to be processed into thin films, which are found to have superior physical stability than the existing products and are thus well suited for low humidity or high temperature electrochemical applications. Moreover, these low-EW ionomers are melt processable and have limited loss of volatile substances at their melt processing temperatures.
Public/Granted literature
- US20150218084A1 ALLYL-BEARING FLUORINATED IONOMERS Public/Granted day:2015-08-06
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