A system for estimating cross-phase modulation (XPM) impairments, wherein the method comprises: determining, according to a pump Jones matrix of a pump channel and a probe Jones matrix of a probe channel of each of fiber spans except for the first fiber span in a fiber transmission system, a polarization mode dispersion (PMD)-induced relative polarization status rotation matrix between channels of the each of fiber spans; and determining, according to the rotation matrix of the each of fiber spans, dispersion of a pump signal of the each of fiber spans, differential delay of the pump signal relative to a probe signal of the each of fiber spans and a gain of the each of fiber spans, polarization crosstalk and phase noise of the XPM impairments in the fiber transmission system. This allows the XPM impairments in the effect of the polarization mode dispersion to be quickly and accurately estimated.