Invention Grant
- Patent Title: Negative electrode for non-aqueous secondary battery, and a non-aqueous secondary battery
- Patent Title (中): 非水二次电池用负极和非水二次电池
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Application No.: US13814069Application Date: 2011-08-03
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Publication No.: US09537139B2Publication Date: 2017-01-03
- Inventor: Naokage Tanaka , Akira Inaba , Keiichiro Uenae , Masayuki Yamada , Kazunobu Matsumoto
- Applicant: Naokage Tanaka , Akira Inaba , Keiichiro Uenae , Masayuki Yamada , Kazunobu Matsumoto
- Applicant Address: JP Osaka
- Assignee: HITACHI MAXELL LTD.
- Current Assignee: HITACHI MAXELL LTD.
- Current Assignee Address: JP Osaka
- Agency: Westerman, Hattori, Daniels & Adrian, LLP
- Priority: JP2010-174270 20100803
- International Application: PCT/JP2011/067731 WO 20110803
- International Announcement: WO2012/018035 WO 20120209
- Main IPC: H01M4/131
- IPC: H01M4/131 ; H01M4/133 ; H01M4/134 ; H01M4/36 ; H01M4/38 ; H01M4/485 ; H01M4/587 ; H01M4/525 ; H01M10/052

Abstract:
[Objectives] The present invention provides a non-aqueous secondary battery in which a material containing Si and O as constituent elements is used in a negative electrode. The present invention provides a non-aqueous secondary battery having good charge discharge cycle characteristics, and suppressing the battery swelling associated with the charge and the discharge. Also, the present invention relates to a negative electrode that can provide the non-aqueous secondary battery. [Solution] The negative electrode includes a negative electrode active material, including a composite of a material containing Si and O as constitution elements (atom ratio x of O to Si is 0.5≦x≦1.5) in combination with a carbon material, and graphite. The graphite has an average particle diameter dg (μm) of 4 to 20 μm. The material containing Si and O as constitution elements has an average particle diameter ds (μm) of 1 μm or more. The ratio ds/dg (i.e., ds to dg) is 0.05 to 1. The material containing Si and O as constitution elements has a crystallite diameter of 50 nm or less, the crystallite diameter is calculated from a half width at a (220) plane of Si obtained by an X-ray diffraction method, using Scherrer Formula. In 100 mass % of the composite of the material containing Si and O as constitution elements, and the carbon material, a ratio of the material containing Si and O as constitution elements is 70 to 95 mass %.
Public/Granted literature
- US20130136988A1 NEGATIVE ELECTRODE FOR NON-AQUEOUS SECONDARY BATTERY, AND A NON-AQUEOUS SECONDARY BATTERY Public/Granted day:2013-05-30
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