Invention Grant
US09540305B2 Process for preparing acrylic acid using an alkali metal-free and alkaline earth metal-free zeolitic material 有权
使用无碱金属和不含碱土金属的沸石材料制备丙烯酸的方法

Process for preparing acrylic acid using an alkali metal-free and alkaline earth metal-free zeolitic material
Abstract:
A process for preparing acrylic acid, comprising (i) providing a stream S4 comprising a formaldehyde source and acetic acid; (ii) contacting stream S4 with an aldol condensation catalyst comprising a zeolitic material comprising aluminum in the framework structure to obtain a stream S6 comprising acrylic acid, the framework structure of the zeolitic material in (ii) comprising YO2 and Al2O3, and Y being a tetravalent element; where the total content of alkali metal and alkaline earth metal in the zeolitic material in (ii), calculated as alkali metal oxide and alkaline earth metal oxide, is from 0% to 0.1% by weight, based in each case on the total weight of the zeolitic material, and where the aldol condensation catalyst in (ii) comprises, outside the framework structure of the zeolitic material present therein, from 0% to 1% by weight of vanadium, based on vanadium as vanadium(V) oxide.
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