Invention Grant
- Patent Title: Method for preparation of ruthenium-based metathesis catalysts with chelating alkylidene ligands
- Patent Title (中): 用螯合亚烷基配体制备钌基复分解催化剂的方法
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Application No.: US14472088Application Date: 2014-08-28
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Publication No.: US09562116B2Publication Date: 2017-02-07
- Inventor: Roland Winde , Angelino Doppiu , Eileen Woerner , Andreas Rivas-Nass , Ralf Karch , Christian Slugovc , Christina Schinagl
- Applicant: UMICORE AG & CO. KG , GRAZ UNIVERSITY OF TECHNOLOGY
- Applicant Address: DE Hanau-Wolfgang AT Graz
- Assignee: UMICORE AG & CO. KG,GRAZ UNIVERSITY OF TECHNOLOGY
- Current Assignee: UMICORE AG & CO. KG,GRAZ UNIVERSITY OF TECHNOLOGY
- Current Assignee Address: DE Hanau-Wolfgang AT Graz
- Agency: Smith, Gambrell & Russell, LLP
- Priority: EP09006204 20090507
- Main IPC: C07F15/00
- IPC: C07F15/00 ; B01J31/12 ; C08F4/80 ; B01J31/22

Abstract:
The invention relates to a method for preparation of ruthenium-based carbene catalysts with a chelating alkylidene ligand (“Hoveyda-type catalysts”) by reacting a penta coordinated ruthenium (II)-alkylidene complex of the type (L) (Py)X1X2Ru(alkylidene) with a suitable olefin derivative in a cross metathesis reaction. The method delivers high yields and is conducted preferably in aromatic hydrocarbon solvents. The use of phosphine-containing Ru carbene complexes as starting materials can be avoided. Catalyst products with high purity, particularly with low Cu content, can be obtained.
Public/Granted literature
- US20140371462A1 METHOD FOR PREPARATION OF RUTHENIUM-BASED METATHESIS CATALYSTS WITH CHELATING ALKYLIDENE LIGANDS Public/Granted day:2014-12-18
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