Invention Grant
- Patent Title: Process for the preparation of (co)polymers of conjugated dienes in the presence of a catalytic system comprising an oxo-nitrogenated complex of cobalt
- Patent Title (中): 在包含含氮的氮化复合物的催化体系存在下制备共轭二烯的(共)聚合物的方法
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Application No.: US14442598Application Date: 2013-12-13
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Publication No.: US09562120B2Publication Date: 2017-02-07
- Inventor: Giovanni Ricci , Giuseppe Leone , Anna Sommazzi , Francesco Masi
- Applicant: Versalis S.P.A.
- Applicant Address: IT
- Assignee: Versalis S.P.A
- Current Assignee: Versalis S.P.A
- Current Assignee Address: IT
- Agency: Abel Law Group, LLP
- Priority: ITMI2012A2203 20121220
- International Application: PCT/IB2013/060905 WO 20131213
- International Announcement: WO2014/097087 WO 20140626
- Main IPC: C08F36/04
- IPC: C08F36/04 ; C08F36/06 ; C08F4/70 ; C08F136/06

Abstract:
Process for the preparation of (co) polymers of conjugated dienes which comprises polymerizing at least one conjugated diene in the presence of a catalytic system comprising at least one oxo-nitrogenated complex of cobalt having general formula (I), wherein: —R1 and R2, equal to or different from each other, represent a hydrogen atom; or they are selected from linear or branched C1-C20, preferably C1-C15, alkyl groups, optionally halogenated; cycloalkyl groups optionally substituted; aryl groups optionally substituted; —Y represents an oxygen atom; or a group —N—R3 wherein R3 represents a hydrogen atom, or it is selected from linear or branched C1-C20 preferably C1-C15, alkyl groups, optionally halogenated, cycloalkyl groups optionally substituted-; aryl groups optionally substituted; or, when Y represents a group —N—R3, R2 and R3 can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched C1-C20 preferably C1-C15, alkyl groups, said cycle optionally containing heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; —X1 and X2, equal to or different from each other, represent a halogen atom such as, for example, chlorine, bromine, iodine; or they are selected from linear or branched C1-C20 preferably C1-C15, alkyl groups, —OCOR4 groups or —OR4 groups wherein R4 is selected from linear or branched C1-C20 preferably C1-C15, alkyl groups.
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