Invention Grant
- Patent Title: Process for preparing cyclic esters and cyclic amides
- Patent Title (中): 制备环酯和环酰胺的方法
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Application No.: US14765703Application Date: 2014-02-07
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Publication No.: US09573924B2Publication Date: 2017-02-21
- Inventor: Bert Sels , Michiel Dusselier
- Applicant: TOTAL RESEARCH & TECHNOLOGY FELUY
- Applicant Address: BE Seneffe
- Assignee: TOTAL RESEARCH & TECHNOLOGY FELUY
- Current Assignee: TOTAL RESEARCH & TECHNOLOGY FELUY
- Current Assignee Address: BE Seneffe
- Agent Albert Shung
- Priority: EP13154707 20130208
- International Application: PCT/EP2014/052493 WO 20140207
- International Announcement: WO2014/122294 WO 20140814
- Main IPC: C07D319/12
- IPC: C07D319/12 ; C07D313/04 ; C07D223/08

Abstract:
A process for preparing a cyclic ester or a cyclic amide includes contacting hydroxycarboxylic acid and/or amino-carboxylic acid, an ester thereof, or a salt thereof, with acidic zeolite. The hydroxycarboxylic acid is a 2- or 6-hydroxycarboxylic acid, and the amino carboxylic acid is a 2- or 6-amino-carboxylic acid. The zeolite may include two or three interconnected and non-parallel channel systems, in which a channel system includes 10- or more-membered ring channels, and in which a framework Si/X2 ratio is at least 24 as measured by NMR. X is Al or B. The zeolite may include three interconnected and non-parallel channel systems, in which at least two channel systems include 10- or more-membered ring channels, and in which a framework Si/X2 ratio is at least 6 as measured by NMR. The process may be performed at a pressure between 0.5 and 20 bar.
Public/Granted literature
- US20150376159A1 Process for Preparing Cyclic Esters and Cyclic Amides Public/Granted day:2015-12-31
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