The present disclosure provides a pixel structure, a manufacturing method of a pixel structure, an array substrate, a display panel, and a display device. The pixel structure includes a plurality of data lines, a plurality of scan lines, a plurality of pixel units and a pixel electrode in each pixel unit including a plurality of slits. An end of the slit includes at least one corner. The white pixel unit includes a first TFT and a second TFT. In a row of pixel units, a first TFT of each white pixel unit is electrically connected to a pixel electrode of the white pixel unit, and a second TFT of each white pixel unit is electrically connected to a pixel electrode of a pixel unit adjacent to the white pixel unit. The corner of the slit in the pixel electrode electrically connected with the second TFT extends toward the second TFT.