The present invention provides a pressure-sensitive adhesive sheet containing a pressure-sensitive adhesive layer that contains a polyester resin as a main component, in which the pressure-sensitive adhesive layer having a laminate structure that contains at least one layer LA where a polyester resin EA having Mw of from 4×104 to 12×104 is crosslinked and at least one layer LB where a polyester resin EB having Mw of from 0.2×104 to 1×104 is crosslinked, and at least one surface of the pressure-sensitive adhesive layer is constituted by the layer LA.