Invention Grant
- Patent Title: Carboxylic acid ester/carbamate compound with polymerizable functional group and fluorine atom group, and manufacturing method therefor
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Application No.: US14910815Application Date: 2015-03-20
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Publication No.: US09604918B2Publication Date: 2017-03-28
- Inventor: Takuhiro Miyamura , Keisuke Kokinn , Sunao Ikeda
- Applicant: UNIMATEC CO., LTD.
- Applicant Address: JP Tokyo
- Assignee: UNIMATEC CO., LTD.
- Current Assignee: UNIMATEC CO., LTD.
- Current Assignee Address: JP Tokyo
- Agency: Squire Patton Boggs (US) LLP
- Priority: JP2014-078190 20140404
- International Application: PCT/JP2015/058619 WO 20150320
- International Announcement: WO2015/151885 WO 20151008
- Main IPC: C07C271/16
- IPC: C07C271/16 ; C07C269/02 ; C07C269/06 ; C08F20/34 ; C08F20/24

Abstract:
Provided are a fluorine-containing monomer soluble in a hydrocarbon-based solvent as well as excellent in water and oil repellence, and a manufacturing method therefor. The fluorine-containing monomer is a carboxylic acid ester/carbamate compound having a polymerizable functional group and a fluorine atom group, and represented by the following general formula: CaF2a+1O—(CbF2bO)c—C2F4COO—Z—(CONHR)d. The method for manufacturing the carboxylic acid ester/carbamate compound is comprised of the steps of making an isocyanate compound having a polymerizable functional group react with an alcohol such as a polyalkylene glycol, a cycloalkane dimethanol, or a polyhydric alcohol to produce a hydroxycarbamate, and subsequently making the resulting hydroxycarbamate react with a perfluoropolyether carboxylic acid halide.
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