Invention Grant
- Patent Title: Method for producing polythiol compound, polymerizable composition for optical material, and uses thereof
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Application No.: US14871479Application Date: 2015-09-30
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Publication No.: US09605105B2Publication Date: 2017-03-28
- Inventor: Masaru Kawaguchi , Takeshi Nishimura
- Applicant: MITSUI CHEMICALS, INC.
- Applicant Address: JP Tokyo
- Assignee: MITSUI CHEMICALS, INC.
- Current Assignee: MITSUI CHEMICALS, INC.
- Current Assignee Address: JP Tokyo
- Agency: Buchanan, Ingersoll & Rooney PC
- Priority: JP2012-179896 20120814
- Main IPC: C08G18/38
- IPC: C08G18/38 ; C07C319/14 ; C07C319/20 ; G02B1/04 ; C07C335/32 ; C07C319/08 ; C07C381/00 ; C08G18/76

Abstract:
Provided is a method for producing a molded product comprising preparing a polymerizable composition for optical materials and curing the polymerizable composition for optical materials to produce the molded product. The preparation of the polymerizable composition comprises preparing a polythiol compound containing, as a main component, one kind or two or more kinds selected from a defined group of compounds, and preparing the polymerizable composition from the polythiol compound. The preparation of the polythiol compound comprises reacting 2-mercaptoethanol with a defined epihalohydrin compound to obtain a defined compound, reacting the defined compound with sodium sulfide to obtain a defined polyalcohol compound, reacting the polyalcohol compound with thiourea in the presence of hydrogen chloride to obtain an isothiuronium salt, adding aqueous ammonia to a reaction solution containing the isothiuronium salt thereby hydrolyzing the isothiuronium salt to obtain the polythiol compound and purifying the polythiol compound with hydrochloric acid.
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