Invention Grant
- Patent Title: High performance Ziegler-Natta catalyst systems, processes for producing such catalyst systems, and use thereof
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Application No.: US14287489Application Date: 2014-05-27
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Publication No.: US09611340B2Publication Date: 2017-04-04
- Inventor: Yvonne Denkwitz , Oliver Schuster , Andreas Winter
- Applicant: Lummus Novolen Technology GmbH
- Applicant Address: DE Mannheim
- Assignee: Lummus Novolen Technology GmbH
- Current Assignee: Lummus Novolen Technology GmbH
- Current Assignee Address: DE Mannheim
- Agency: Osha • Liang LLP
- Main IPC: B01J31/00
- IPC: B01J31/00 ; B01J37/00 ; C08F4/02 ; C08F4/60 ; C08F110/06 ; C08F10/06

Abstract:
A catalyst system for the polymerization of olefins may include a first solid catalytic component and a second solid catalytic component. The first solid catalytic component may include: a spherical MgCl2-xROH support; a group 4-8 transition metal; and a diether internal electron donor. The second solid catalytic component may include: a spherical MgCl2-xROH support; a group 4-8 transition metal; and a diether internal electron donor. The first solid catalytic component produces a propylene homopolymer having a Xylene Solubles (XS) value of greater than 2 wt %; and the second solid catalytic component produces a propylene homopolymer having a XS value of less than 2 wt %. The second catalytic component may act as an external electron donor during use, and embodiments herein do not require use of any additional external electron donors to control polymerization and reliably vary the properties of the resulting polymer.
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