An Al film is formed so that film forming particles are incident at normal incidence to grating wall surfaces of a diffraction grating having multiple grating portions and are incident at oblique incidence to optical effective surfaces. After that, oxidation treatment is performed from a direction to be incident at normal incidence to the optical effective surface so that the Al layer on the optical effective surface is changed to Al2O3 layer. Hence, in the diffraction grating having the multiple grating portions, the Al2O3 layer is formed on the optical effective surface for transmitting light, and the Al layer is formed on the grating wall surfaces as a light shielding layer. Thus, flare of the diffractive optical element can be suppressed.