The present invention provides a pixel structure disposed on a substrate, and the pixel structure includes an alignment layer, a common electrode, and a pixel electrode. The alignment layer is disposed on the substrate, and the alignment layer has a first section and a second section. The first section has a first alignment direction, and the second section has a second alignment direction perpendicular to the first alignment direction. The common electrode is disposed between the substrate and the alignment layer, and the pixel electrode is disposed between the substrate and the alignment layer.