The stack-folding type electrode assembly according to the present disclosure is an electrode assembly including a plurality of stack type unit cells which is stacked on one another with a continuous folding separator sheet interposed between each of the stacked unit cells, wherein the unit cells has a combination of at least two quad cells of a positive electrode/separator/negative electrode/separator/positive electrode/separator/negative electrode structure, and one C-type bicell of a negative electrode/separator/positive electrode/separator/negative electrode structure, and unit cells disposed above and below a central part or a winding start point have an asymmetrical structure each other with the quad cell disposed at the central part, or unit cells disposed above and below a central part or a winding start point have a symmetrical structure each other with the C-type bicell disposed at the central part.