Invention Grant
- Patent Title: Method to produce furandicarboxylic acid (FDCA) from 5-hydroxymethylfurfural (HMF)
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Application No.: US14974468Application Date: 2015-12-18
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Publication No.: US09617234B1Publication Date: 2017-04-11
- Inventor: James A. Dumesic , Ali Hussain Motagamwala
- Applicant: Wisconsin Alumni Research Foundation
- Applicant Address: US WI Madison
- Assignee: Wisconsin Alumni Research Foundation
- Current Assignee: Wisconsin Alumni Research Foundation
- Current Assignee Address: US WI Madison
- Agency: DeWitt Ross & Stevens S.C.
- Agent Joseph T. Leone, Esq.
- Main IPC: C07D307/02
- IPC: C07D307/02 ; C07D307/68

Abstract:
A process to produce furandicarboxylic acid (FDCA). The process includes the steps of reacting a C6 sugar-containing reactant in a reaction solution comprising a first organic solvent selected from the group consisting of beta-, gamma-, and delta-lactones, hydrofurans, hydropyrans, and combinations thereof, in the presence of an acid catalyst for a time and under conditions wherein at least a portion of the C6 sugar present in the reactant is converted to 5-(hydroxymethyl)furfural (HMF); oxidizing the HMF into FDCA with or without separating the HMF from the reaction solution; and extracting the FDCA by adding an aprotic organic solvent having a dipole moment of about 1.0 D or less to the reaction solution.
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